Latest Inventions Technologies of salvaging TECHNIQUE AND EQUIPMENT FOR THERMAL PROCESSING OF RADIOACTIVE ION-EXCHANGE RESINS
TECHNIQUE AND
EQUIPMENT FOR THERMAL PROCESSING OF RADIOACTIVE ION-EXCHANGE RESINS
The known technique provides for making a mixture
by stirring, within a mixing zone, of radioactive ion-exchange resins with
powdered metallized fuel which comes in the form of a metallized charge
containing the calcium-silicon alloy and the aluminum-magnesium alloy, both
powdered, and 2-10 percent of the total mass of the metallized charge of the
sodium nitrate or potassium nitrate in which 2-4 percent of the industrial oil
of the total mass of the powdered metallized fuel has been added. This is
followed by feeding the mixture to the thermal decomposition zone, applying, to
the surface of the mixture, the layer of the powdered low-gas contact warming
compound or the mixture of powdered aluminum with ВаО2
and КСlО3 in amount of 1-2 percent of
the total mass of the mixture, igniting this layer provided the oxidizer is
present in the thermal decomposition zone, separating the gases outgoing from
the accumulating slag within the zone of thermal decomposition and, finally,
taking them from the thermal decomposition zone over for filter cleaning.
The new technique is different in that the
metallized charge has a specific area of 100-500 m/kg and contains additionally
the powered aluminum in amount of 3-10 percent of the total mass of the
metallized charge and the powdered silicon in the form of its mixture in any
proportion with the powdered silicocalcium, the silicon-silicocalcium mixture
content being 50-65 percent of the total mass of the metallized charge, while
the powdered aluminum-magnesium alloy content is 30-40 percent of the total mass
of the metallized charge. Additionally, a blowing agent is added to the mixture
of the radioactive ion-exchange resins and powdered metallized fuel that is
being stirred in the mixing zone. The mass percentage of the composition of the
mixture resulting therein should be as follows:
the radioactive ion-exchange resins – 75-85
percent;
the powdered metallized fuel – 5-19 percent;
and
the blowing agent – 5-10 percent.
The layer to be ignited is applied to cover the
entire surface of the mixture, and the air is used as an oxidizer whose presence
in the thermal decomposition zone is ensured by making it go down through the
layer of the powdered low-gas contact warming composition, or the composition of
the powdered aluminum with ВаО2 and
КСlО3, and the mixture of the radioactive
ion-exchange resins, powdered metallized fuel and blowing agent.
The slag produced after its separation from the
outgoing gases in the thermal decomposition zone is further fed to the final
oxidation zone, the outgoing gases are, then, taken from the thermal
decomposition zone, mixed with air and, before being sent for filtering, the
resultant gas mixture is fed to the final oxidation zone where it is blown
through the slag brought thereto.
The second variant of the technique proposed
provides for a specified composition of the blowing agent which can be either
dry wood sawdust or Aerosil.
The patent gives a detailed description of the
equipment required for the technique proposed.
I. A. Sobolev and others
2/14, 7th Rostovsky Pereulok, 1191121 Moscow
Moscow State Enterprise – The Unified
Environment Technology Research Center for Neutralization of Radioactive Waste
and Environment Protection (Moscow Research and Production Association “RADON”,
c/o I.A.Sobolev, Director-General)
Patent number: 2153718
Publishing date: September 25, 2000
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