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Technology Database    Ecology MAGNETOACTIVE ION-EXCHANGER FOR REMOVAL OF HEAVY METALS AND RADIONUCLIDES IN ENVIRONMENT

Magnetoactive ion-exchanger for removal of heavy metals and radionuclides in environment

Purpose

Ferromagnetic ion-exchanger can be used for removal of heavy metals and radionuclides from soils, silts and highly turbid solution. The properties of ferromagnetic ion exchanger allow to carry out de-contamination of water in batch mode.

Distinguishing properties

Sorbent is prepared on the basis of natural zeolite material clinoptilolite-bearing tuffs. It is characterized by ion-exchange properties and considerable magnetic susceptibility.

The prepared sorbent has improved mechanical properties as compared to initial materials.

Basic physical-chemical characteristics

Grain size

0,05 - 0,50 mm

Cation exchange capacity

1,0 -1,8 meq/g

Magnetic susceptibility

(5 -23)· 10-3 unit CGSM, depending on procedure of sorbent preparation and its grain size

Distribution coefficient from drinking water (contact time 1 month):

 

for Sr

>103

for heavy metals

>103

for Cs

>104

The preparation of ferromagnetic sorbent

The solutions of salts FeS04 and FeCl3 are poured into the flask in the molar ratio of 1 to 2. The mixture is heated to 80-90oС, then the 17-20% solution of NaOH or NH4OH is added in excess and the mixture is stirred. The black precipitate of magnetic is formed. The natural zeolite-cloniptilolite is added and the mixture is heated to boiling and is hold at this temperature during 1,0 - 1,5 hours, then cooled. The excess of magnetic removed by decanting or by sieving. The sorbent obtained is easily separated from nonmagnetic impurities with magnet.

Patent protection

  • Patent RF № 2081846.

Suggestions

Institute can provide the following on commercial basis:

  1. specimens of sorbent for on-the-spot inspection;
  2. instructing personnel for using the sorbent;
  3. combined organization of commercial production;
  4. joint use of sorbent for decontamination of soils, silts and highly turbid solutions.

Authors: I.B. Serova, V.A. Nikaschina, B.A. Rudenko.

Publishing date: April 26, 2001

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