Technology Database Ecology MAGNETOACTIVE ION-EXCHANGER FOR REMOVAL OF HEAVY METALS AND RADIONUCLIDES IN ENVIRONMENT
Magnetoactive
ion-exchanger for removal of heavy metals and radionuclides in environment
Purpose
Ferromagnetic ion-exchanger can
be used for removal of heavy metals and radionuclides from soils, silts and
highly turbid solution. The properties of ferromagnetic ion exchanger allow to
carry out de-contamination of water in batch mode.
Distinguishing properties
Sorbent is prepared on the basis
of natural zeolite material clinoptilolite-bearing tuffs. It is characterized by
ion-exchange properties and considerable magnetic susceptibility.
The prepared sorbent has improved
mechanical properties as compared to initial materials.
Basic physical-chemical
characteristics
|
Grain size |
0,05 - 0,50 mm |
|
Cation exchange capacity |
1,0 -1,8 meq/g |
|
Magnetic susceptibility |
(5 -23)· 10-3
unit CGSM, depending on procedure of sorbent preparation and its grain
size |
|
Distribution coefficient
from drinking water (contact time 1 month): |
|
|
for Sr |
>103 |
|
for heavy metals |
>103 |
|
for Cs |
>104 |
The preparation of ferromagnetic
sorbent
The solutions of salts FeS04
and FeCl3 are poured into the flask in the molar ratio of 1 to 2. The
mixture is heated to 80-90oС, then the 17-20% solution of NaOH or NH4OH
is added in excess and the mixture is stirred. The black precipitate of magnetic
is formed. The natural zeolite-cloniptilolite is added and the mixture is heated
to boiling and is hold at this temperature during 1,0 - 1,5 hours, then cooled.
The excess of magnetic removed by decanting or by sieving. The sorbent obtained
is easily separated from nonmagnetic impurities with magnet.
Patent protection
Suggestions
Institute can provide the
following on commercial basis:
- specimens of sorbent for on-the-spot
inspection;
- instructing personnel for using the sorbent;
- combined organization of commercial production;
- joint use of sorbent for decontamination of
soils, silts and highly turbid solutions.
Authors: I.B.
Serova, V.A. Nikaschina, B.A. Rudenko.
Publishing date: April 26, 2001
To make an inquiry on the technology you are interested in
Back
|